Properties of Compounds
How the type of chemical bond determines the physical behavior of substances
Properties of compounds are directly determined by the type of chemical bonding present. Understanding these relationships helps predict how substances will behave in different situations.
1. Melting and Boiling Points
Ionic Compounds
HIGH melting & boiling points
HighStrong electrostatic forces between ions in the crystal lattice require significant energy to overcome.
Example: NaCl melts at 801°C, boils at 1465°C
Covalent (Molecular)
LOW melting & boiling points
LowWeak intermolecular forces between molecules require little energy to overcome.
Example: H₂O boils at 100°C, CH₄ boils at -161°C
Giant Covalent
VERY HIGH melting points
Extremely HighExtensive networks of covalent bonds create a robust framework requiring enormous energy to break.
Examples: Diamond, Graphite, Silica (SiO₂) - all melt above 3500°C
Rank the Melting Points
Click on the compound with the HIGHEST melting point:
2. Electrical Conductivity
Ionic Compounds
Solid: No conductivity (ions fixed in lattice)
Molten/Aqueous: Conducts (ions free to move)
Covalent Compounds
Non-conductors in all states (no free ions/electrons)
Exception: Graphite conducts electricity due to delocalised electrons in its layers.
Conductivity Challenge
Will this substance conduct electricity?
3. Solubility
Ionic Compounds
Soluble in polar solvents (like water)
Water molecules interact with charged ions, pulling them apart.
Example: NaCl dissolves in water
Covalent Compounds
Non-polar: Soluble in non-polar solvents (oil, benzene)
Polar covalent: May dissolve in water (e.g., sugar)
Examples: Oil in petrol (soluble), Sugar in water (soluble), Wax in water (insoluble)
Solubility Quick Check
Which statement is TRUE?
4. Malleability and Brittleness
Ionic Solids
Brittle - shatter when force is applied
When force is applied, like charges align and repel each other, causing the crystal to shatter.
Summary of Properties by Bond Type
| Property | Ionic | Covalent (Molecular) | Giant Covalent | Metallic |
|---|---|---|---|---|
| Melting/Boiling Points | High | Low | Very High | High |
| Electrical Conductivity | Only when molten/aqueous | Poor (except graphite) | Poor (except graphite) | Excellent |
| Solubility | Soluble in polar solvents | Soluble in non-polar solvents | Insoluble | Insoluble (except in acids) |
| Malleability | Brittle | Brittle (molecular crystals) | Brittle | Malleable & Ductile |
Test Your Understanding
1. Why do ionic compounds have high melting points?
2. When do ionic compounds conduct electricity?
3. Which property allows metals to be drawn into wires?
4. Which is an exception to the rule that covalent compounds don't conduct electricity?
Key Terms
Key Takeaways
- Ionic compounds: High melting points, conduct when molten/aqueous, soluble in water, brittle
- Covalent molecular: Low melting points, non-conductors, soluble in non-polar solvents, brittle
- Giant covalent: Very high melting points, non-conductors (except graphite), insoluble, brittle
- Metallic: High melting points, excellent conductors, insoluble, malleable and ductile
- Graphite is an exception - covalent but conducts due to delocalised electrons
- Properties are determined by bond type and structure